Acetylation between alcohol and benzoyl oxide was carried out using znbr2 as a lewis acid catalyst in solvent - free condition . some structures were characterized by nmr and ir 以溴化锌为催化剂,在无溶剂条件下实现了醇与苯甲酸酐的酰化反应,部分产物经nmr和ir表征。
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Acetylation between alcohol and benzoyl oxide was carried out using znbr2 as a lewis acid catalyst in solvent - free condition . some structures were characterized by nmr and ir 摘要以溴化锌为催化剂,在无溶剂条件下实现了醇与苯甲酸酐的酰化反应,部分产物经nmr和ir表征。
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Chelating and detoxification metal ions are also the focus of many researchers . according to lewis soft - hard acid - base theory , aluminum is the hardest trivancy lewis acid , and polyphenols are lewis base theoretically , they can combine together tightly 根据lewis软硬酸碱理论,铝是三价金属离子中最硬的lewis酸,而多酚类却是lewis碱(电子对供体,亲核体) ,两者可以很好的结合。
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They were used as efficient lewis acid catalysts for esterification reactions of carboxylic acids with alcohols to afford corresponding saturated esters with 87 % ~ 98 % yields and unsaturated and tertiary ones with 90 % ~ 94 % and 54 % ~ 68 % yields , respectively 结果表明,该有机锡化合物是合成酯的优良催化剂,产品收率高,饱和一元羧酸酯的收率为87 % ~ 98 % ,对不饱和羧酸酯和空间位阻大的叔醇酯也能得到较满意的收率,分别为90 % ~ 94 %和54 % ~ 68 % 。
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The enhanced photoconductive effect from small amount of tnf facilitates the preparations of new organic photoconductive devices under the drive of low fields . in the fourth chapter , inclpc nanoparticles embedded in poly ( n - vinylcarbzaole ) ( pvk ) were prepared successfully by dissolving inclpc in aprotic organic solvent / lewis acid with great concentration for the formation of electron donor - acceptor complexes , i . e . , the method of complexation - mediated solubilization . the fabricated inclpc nanoparticles were characterized by means of uv / vis absorption , x - ray diffraction pattern , and tem 论文的最后一章中,我们合成了具有较好的电子传输性能的化合物’一二苯基四竣酸花酚亚胺( ddp ) ;研究了其溶解性、热稳定性、晶体结构、红外光谱、紫外吸收光谱和蒸镀薄膜的属性,并用量子化学计算方法模拟其单分子的空间构型;载流子迁移率测试的结果约为ix10 “ 、 m ’ v ” ’ ? s “ ’ 。